Fig. 3: Residual map showing the oscillatory modulation of the A2D signal averaged along the exciton region. | Nature Communications

Fig. 3: Residual map showing the oscillatory modulation of the A2D signal averaged along the exciton region.

From: Phonon-driven intra-exciton Rabi oscillations in CsPbBr3 halide perovskites

Fig. 3

a, b For T < 2 ps (a), the residuals show fast, 107 fs (310 cm−1) oscillations and (b) a dispersive lineshape centered around the maximum of the 2DES cross-section (cf. Figure 1d) at E0 + δ (dashed line in b). c, d For T > 2 ps (c), oscillations at ~30 cm−1 and 50 cm−1 (FT map in the inset. See also Figs. S5, 6) with (d) an absorptive lineshape centered around E0 (dashed line in d) are observed. This lineshape matches the predictions of a displaced harmonic oscillator model, showing that the oscillations reflect low-frequency coherent phonon wavepacket motion. The fast oscillations in (a) go beyond the displaced harmonic oscillator model and are assigned to intra-exciton Rabi oscillations.

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