Table 1 Performance of Ru pyrochlores for the OER in acidic electrolytes

From: Active and durable R2MnRuO7 pyrochlores with low Ru content for acidic oxygen evolution

 

j/mA cm−2geo @ 1.5 V

E-iR/V @ 10 mA cm−2geo

Tafel slope/mV dec−1

Ru mass-specific activity/A g−1Ru

Durability tests RDE

Y2RuMnO7 (this work)

12

1.49

48

795 @ 1.55 V

45 h @ Ej = 10

Dy2RuMnO7 (this work)

6.5

1.51

47

707 @ 1.55 V

25 h @ Ej = 10

Tb2RuMnO7 (this work)

2.5

1.54

56

335 @ 1.55 V

15 h @ Ej = 10

Y2Ru2O7 (this work)

3.1

1.52

46

245 @ 1.55 V

 

Y2Ru2O722

[email protected] V‡*

1.561(5)

40

~500 @ 1.55 V*

~ 8 h @ 1.56 V

Nd2Ru2O722

[email protected] V‡*

1.576(9)

41

~350 @ 1.55 V*

~ 4 h @ 1.56 V

Gd2Ru2O722

[email protected] V‡*

1.590(7)

47

~250 @ 1.55 V*

~ 6 h @ 1.56 V

Bi2Ru2O722

[email protected] V‡*

1.588(7)

48

~250 @ 1.55 V*

~6 h @ 1.56 V

Y1.85Ba0.15Ru2O7-δ23

6.9

1.508

40.8

-

1500 cycles bt. 1.4–1.6 V

Y1.7Sr0.3Ru2O725

 

1.494

44.8

1018 @ 1.53 V

 

Y1.85Zn0.15Ru2O7-δ26

4.4

1.521

36.9

-

2000 cycles bt. 1.35–1.6 V

Y2[Ru1.6Y0.4]O7-δ30

18.1

1.48

37

700 @ 1.5 V

-

Y1.8Fe0.2Ru2O7-δ29

0

1.625*

57–63

~400 @ 1.625 V*

-

Y1.8Cu0.2Ru2O7-δ29

>1

1.58*

57–63

~400 @ 1.55 V*

6 h @ 1 mA cm−2geo

Y1.8Ni0.2Ru2O7-δ29

>1

-

57–63

~400 @ 1.575 V*

-

Y1.8Co0.2Ru2O7-δ29

0

-

57–63

~400 @ 1.585 V*

-

Y2Ru2O7-δ29

>1

1.58*

57–63

~400 @ 1.55 V*

-

Yb2Ru2O79

   

650 @ 1.58 V

-

RuO222

1.2 @ 1.55 V

1.626 (14)

77

 

-

  1. Unless otherwise stated, the activity of the first OER cycle is reported.
  2. *Activity values extracted from the figures of the indicated references.
  3. OER at 10th cycle.
  4. OER at the 100th cycle.