Table 1 Performance of Ru pyrochlores for the OER in acidic electrolytes
From: Active and durable R2MnRuO7 pyrochlores with low Ru content for acidic oxygen evolution
j/mA cm−2geo @ 1.5 V | E-iR/V @ 10 mA cm−2geo | Tafel slope/mV dec−1 | Ru mass-specific activity/A g−1Ru | Durability tests RDE | |
---|---|---|---|---|---|
Y2RuMnO7 (this work) | 12† | 1.49† | 48† | 795 @ 1.55 V† | 45 h @ Ej = 10 |
Dy2RuMnO7 (this work) | 6.5† | 1.51† | 47† | 707 @ 1.55 V† | 25 h @ Ej = 10 |
Tb2RuMnO7 (this work) | 2.5† | 1.54† | 56† | 335 @ 1.55 V† | 15 h @ Ej = 10 |
Y2Ru2O7 (this work) | 3.1† | 1.52† | 46† | 245 @ 1.55 V† | |
Y2Ru2O722 | 1.561(5)‡ | 40‡ | ~500 @ 1.55 V* | ~ 8 h @ 1.56 V | |
Nd2Ru2O722 | 1.576(9)‡ | 41‡ | ~350 @ 1.55 V* | ~ 4 h @ 1.56 V | |
Gd2Ru2O722 | 1.590(7)‡ | 47‡ | ~250 @ 1.55 V* | ~ 6 h @ 1.56 V | |
Bi2Ru2O722 | 1.588(7)‡ | 48‡ | ~250 @ 1.55 V* | ~6 h @ 1.56 V | |
Y1.85Ba0.15Ru2O7-δ23 | 6.9 | 1.508 | 40.8 | - | 1500 cycles bt. 1.4–1.6 V |
Y1.7Sr0.3Ru2O725 | 1.494 | 44.8 | 1018 @ 1.53 V | ||
Y1.85Zn0.15Ru2O7-δ26 | 4.4 | 1.521 | 36.9 | - | 2000 cycles bt. 1.35–1.6 V |
Y2[Ru1.6Y0.4]O7-δ30 | 18.1 | 1.48 | 37 | 700 @ 1.5 V | - |
Y1.8Fe0.2Ru2O7-δ29 | 0 | 1.625* | 57–63 | ~400 @ 1.625 V* | - |
Y1.8Cu0.2Ru2O7-δ29 | >1 | 1.58* | 57–63 | ~400 @ 1.55 V* | 6 h @ 1 mA cm−2geo |
Y1.8Ni0.2Ru2O7-δ29 | >1 | - | 57–63 | ~400 @ 1.575 V* | - |
Y1.8Co0.2Ru2O7-δ29 | 0 | - | 57–63 | ~400 @ 1.585 V* | - |
Y2Ru2O7-δ29 | >1 | 1.58* | 57–63 | ~400 @ 1.55 V* | - |
Yb2Ru2O79 | 650 @ 1.58 V | - | |||
RuO222 | 1.2 @ 1.55 V | 1.626 (14) | 77 | - |