Fig. 4: Development of a fully biocatalytic platform for asymmetric α-methylation with a record turnover efficiency.

a Mining of Pseudomonas HMTs: sequence similarity network (SSN) of selected putative HMTs. b Dual biocatalytic enantioselective methylation using SgvMVAV and HMTs mined from Pseudomonas species. PaHMT: P. aeruginosa HMT, PeHMT: P. entomophila HMT, PfHMT: P. fluorescens HMT, PpHMT: P. putida HMT, PsHMT: P. syringae HMT. a0.01 mol% PaHMT was used. c SAM regeneration efficiency with HMTs from Pseudomonas sp.