Fig. 2: DSC measurement results for all PDMS networks.

a Heat flow curves for Pend-3.5 with different dynamic bond ratios (different colors). b Heat flow curves for Pend-5.8 with different dynamic bond ratio (different colors). c Heat flow curves for telechelic PDMS with different dynamic bond ratios (different colors). The step on each curve is labeled by dashed line indicating Tg for each polymer. The value of Tg is labeled in each graph. The exothermic direction of heat flow is labeled by an arrow in each graph. d Tg as a functional of initial NH2 percentage on the PDMS backbone (Pendant: red; Telechelic: green; PDMS without functional group: black). The Tg of PDMS without any functional groups corresponds to PDMS with molecular weight of 5940 g/mol70.