Fig. 3: Substrate scope of monosubstituted alkenes.a | Nature Communications

Fig. 3: Substrate scope of monosubstituted alkenes.a

From: Umpolung reactivity of strained C–C σ-bonds without transition-metal catalysis

Fig. 3

a Reaction conditions A: BCB 1 (0.2 mmol), alkene 2 (0.1 mmol), Na2SO4 (0.17 mmol), 80 °C in DMSO (0.1 mL) under argon, 24 h, isolated yield. b 100 °C. c neat without any solvent, BCB 1 (0.1 mmol), alkene 2 (0.5 mmol), Na2SO4 (0.17 mmol). d Reaction conditions B:BCB 1 (0.1 mmol), alkene 2 (0.4 mmol), Na2SO4 (0.17 mmol), 80 °C in DMSO (0.1 mL). e MgSO4 instead of Na2SO4. f 40 °C.

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