Table 2 Contents of flavonoid derivatives according to the aglycones and glycosides in young leaves of 21 soybean cultivars (mg/100 g, dry weight).

From: Comprehensive characterization of flavonoid derivatives in young leaves of core-collected soybean (Glycine max L.) cultivars based on high-resolution mass spectrometry

Glycosides

Peak No

Shinpaldal2ho (SL1)

Daewon kong (SL2)

Cheongja 2 (SL3)

SL4

SL5

SL6

SL7

SL8

SL9

SL10

SL11

SL12

SL13

SL14

SL15

SL16

SL17

SL18

SL19

SL20

SL21

Flavonols (55)

Quercetin derivatives (18)

Mono

40

ND

ND

1.1 ± 0.1

1.5 ± 0.1

ND

ND

ND

1.1 ± 0.3

ND

7.2 ± 0.2

4.8 ± 0.7

4.6 ± 0.6

1.2 ± 0.3

ND

7.1 ± 0.6

0.8 ± 0.3

6.3 ± 0.8

13.0 ± 1.1

0.8 ± 0.4

6.0 ± 0.0

ND

46

2.0 ± 0.3

ND

1.4 ± 0.3

1.8 ± 0.1

ND

ND

ND

3.7 ± 0.2

ND

13.0 ± 0.2

8.4 ± 0.4

6.8 ± 0.4

2.1 ± 0.2

ND

11.5 ± 1.0

2.1 ± 0.4

6.1 ± 0.5

42.0 ± 1.1

3.9 ± 0.9

7.6 ± 0.0

ND

Di

8

1.4 ± 0.3

ND

10.0 ± 0.2

ND

0.4 ± 0.1

0.6 ± 0.0

1.1 ± 0.3

10.6 ± 0.3

ND

106.9 ± 6.4

58.1 ± 2.5

32.1 ± 0.6

4.7 ± 0.6

ND

113.9 ± 11.3

2.4 ± 0.4

12.2 ± 0.4

2.3 ± 0.5

8.1 ± 0.5

2.1 ± 0.1

ND

11

1.0 ± 0.1

ND

10.3 ± 0.2

ND

ND

0.3 ± 0.0

0.6 ± 0.1

11.6 ± 0.6

ND

146.1 ± 8.2

72.7 ± 5.9

48.2 ± 0.4

3.5 ± 0.2

ND

164.9 ± 12.1

2.4 ± 0.6

13.3 ± 0.4

4.3 ± 0.6

7.2 ± 0.6

2.3 ± 0.3

ND

18a

ND

ND

ND

11.2 ± 0.2

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

20a

ND

ND

ND

27.2 ± 0.2

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.1 ± 0.1

ND

ND

ND

24

ND

ND

ND

ND

ND

ND

ND

ND

ND

11.5 ± 0.8

7.2 ± 0.6

12.5 ± 2.9

ND

ND

10.5 ± 1.2

ND

ND

17.1 ± 0.6

ND

ND

ND

25a

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.4 ± 0.2

ND

ND

8.9 ± 0.7

ND

1.5 ± 0.3

ND

ND

4.7 ± 0.5

ND

ND

ND

35

18.6 ± 1.1

ND

2.8 ± 0.3

16.2 ± 3.2

ND

ND

ND

10.1 ± 1.1

ND

ND

ND

19.6 ± 1.4

9.7 ± 0.4

ND

ND

15.3 ± 1.5

29.9 ± 0.3

ND

12.6 ± 1.8

61.9 ± 4.8

ND

38

41.5 ± 1.7

ND

3.6 ± 0.3

36.8 ± 1.2

0.7 ± 0.1

ND

ND

18.0 ± 1.2

ND

ND

ND

45.3 ± 0.7

ND

ND

ND

28.3 ± 0.7

65.6 ± 1.4

ND

23.2 ± 0.6

176.7 ± 9.1

ND

Tri

1a

ND

ND

ND

2.1 ± 0.5

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

2a

ND

ND

ND

2.1 ± 0.9

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

3a

ND

ND

ND

13.3 ± 0.3

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

5a

ND

ND

ND

1.4 ± 0.3

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

6

2.0 ± 0.3

1.3 ± 0.0

22.3 ± 1.2

ND

0.6 ± 0.1

0.6 ± 0.1

ND

69.9 ± 5.6

0.5 ± 0.1

ND

ND

76.3 ± 4.6

56.5 ± 1.7

ND

ND

1.5 ± 0.2

85.8 ± 3.7

ND

59.4 ± 7.2

4.0 ± 0.0

ND

7

1.0 ± 0.2

1.5 ± 0.1

21.3 ± 0.7

1.1 ± 0.1

0.7 ± 0.1

0.5 ± 0.2

ND

86.0 ± 6.1

ND

ND

ND

101.8 ± 5.7

46.3 ± 1.5

ND

ND

1.0 ± 0.2

113.8 ± 4.6

ND

80.6 ± 7.0

5.3 ± 0.2

ND

13a

17.4 ± 0.3

ND

4.0 ± 0.1

13.8 ± 0.2

ND

ND

ND

15.1 ± 1.0

ND

ND

ND

18.3 ± 0.4

15.1 ± 0.6

ND

ND

8.5 ± 0.5

41.0 ± 0.7

ND

18.1 ± 1.3

78.2 ± 0.4

ND

14

1.2 ± 0.1

ND

ND

0.9 ± 0.0

ND

ND

ND

0.8 ± 0.1

ND

ND

ND

1.6 ± 0.1

0.7 ± 0.1

ND

ND

ND

2.4 ± 0.2

ND

1.3 ± 0.1

5.4 ± 0.3

ND

Subtotal

86.2 ± 2.2

2.8 ± 0.1

76.6 ± 2.6

129.3 ± 8.1

2.3 ± 0.1

2.0 ± 0.3

1.6 ± 0.4

226.9 ± 14.2

0.5 ± 0.1

286.0 ± 15.2

151.3 ± 7.9

367.2 ± 12.8

148.7 ± 2.4

ND

309.4 ± 25.6

62.2 ± 0.9

376.3 ± 9.7

84.5 ± 2.1

215.2 ± 15.2

349.6 ± 16.3

ND

Kaempferol derivatives (20)

Mono

57a

1.4 ± 0.1

2.1 ± 0.1

1.5 ± 0.1

0.5 ± 0.1

15.1 ± 1.2

7.9 ± 0.2

15.8 ± 0.7

4.8 ± 0.2

8.4 ± 0.4

8.3 ± 0.4

14.8 ± 0.7

2.1 ± 0.0

2.4 ± 0.0

3.4 ± 0.2

3.9 ± 0.4

3.8 ± 0.1

2.5 ± 0.1

34.4 ± 0.4

1.5 ± 0.1

2.5 ± 0.3

20.7 ± 0.8

63

1.5 ± 0.3

1.4 ± 0.0

1.1 ± 0.1

1.0 ± 0.2

15.4 ± 1.2

5.5 ± 0.4

11.8 ± 1.0

4.0 ± 0.6

6.2 ± 0.4

3.2 ± 0.1

8.3 ± 0.2

2.3 ± 0.5

0.8 ± 0.1

2.3 ± 0.1

2.2 ± 0.2

5.0 ± 1.2

2.5 ± 0.6

65.8 ± 0.3

1.3 ± 0.4

2.8 ± 0.6

12.4 ± 0.6

Di

26

1.3 ± 0.3

12.9 ± 0.3

17.4 ± 0.1

ND

ND

49.7 ± 0.2

303.6 ± 9.8

31.2 ± 6.0

56.5 ± 2.5

69.8 ± 2.5

179.0 ± 5.0

21.9 ± 0.6

6.7 ± 0.5

26.8 ± 3.6

61.1 ± 6.5

3.7 ± 0.9

7.3 ± 1.3

7.2 ± 0.3

7.6 ± 0.8

9.1 ± 0.4

258.0 ± 11.5

28

ND

5.4 ± 0.2

12.1 ± 0.7

ND

ND

24.7 ± 0.4

218.8 ± 6.5

17.7 ± 1.0

31.1 ± 0.5

55.6 ± 2.9

126.4 ± 4.3

18.0 ± 0.7

2.3 ± 0.1

15.8 ± 0.1

54.2 ± 3.6

4.6 ± 1.0

4.7 ± 0.2

6.8 ± 0.5

3.5 ± 0.3

2.0 ± 0.2

192.5 ± 8.6

30a

ND

ND

ND

9.1 ± 0.5

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.4 ± 0.2

ND

ND

ND

37

0.5 ± 0.1

0.5 ± 0.0

1.4 ± 0.1

ND

5.0 ± 0.2

2.8 ± 0.1

45.0 ± 2.7

1.9 ± 0.0

4.4 ± 0.2

24.8 ± 1.0

42.6 ± 1.1

8.7 ± 0.3

0.9 ± 0.1

2.0 ± 0.1

11.3 ± 0.9

1.4 ± 0.2

0.7 ± 0.1

64.7 ± 2.7

0.6 ± 0.1

0.4 ± 0.0

1.7 ± 0.1

39

ND

ND

ND

11.4 ± 1.1

0.8 ± 0.1

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

43a

ND

ND

ND

ND

1.0 ± 0.2

0.5 ± 0.1

6.4 ± 0.3

ND

0.8 ± 0.2

1.7 ± 0.1

5.7 ± 0.6

2.3 ± 0.1

ND

0.4 ± 0.1

1.3 ± 0.1

ND

ND

23.2 ± 2.0

ND

ND

ND

54

31.8 ± 0.8

18.5 ± 0.9

5.3 ± 0.1

13.2 ± 0.5

171.4 ± 13.3

31.5 ± 1.4

ND

22.2 ± 1.0

29.5 ± 1.5

ND

ND

16.7 ± 0.3

12.8 ± 0.4

20.0 ± 0.7

ND

71.2 ± 2.7

28.8 ± 0.8

ND

9.6 ± 0.6

41.0 ± 1.9

ND

58

41.3 ± 2.6

16.8 ± 0.6

4.8 ± 0.2

16.9 ± 0.9

245.6 ± 17.6

31.1 ± 1.0

ND

19.2 ± 1.4

32.1 ± 1.2

ND

ND

17.0 ± 0.8

6.8 ± 0.2

19.7 ± 0.5

ND

73.9 ± 4.3

33.7 ± 1.3

ND

9.6 ± 0.4

62.7 ± 0.9

ND

52a

ND

ND

0.2 ± 0.0

ND

ND

ND

1.3 ± 0.5

ND

ND

0.6 ± 0.1

ND

ND

ND

ND

0.6 ± 0.0

ND

ND

ND

ND

ND

2.6 ± 0.6

53a

ND

ND

ND

ND

ND

ND

0.7 ± 0.2

ND

ND

0.2 ± 0.1

ND

ND

ND

ND

0.4 ± 0.0

ND

ND

ND

ND

ND

1.6 ± 0.4

Tri

4a

ND

ND

ND

2.4 ± 0.4

ND

0.7 ± 0.0

3.6 ± 0.2

ND

1.5 ± 0.1

ND

2.9 ± 0.3

ND

ND

ND

ND

ND

ND

ND

ND

ND

10.2 ± 1.5

10

ND

ND

ND

9.9 ± 0.5

0.6 ± 0.0

ND

1.0 ± 0.1

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

3.0 ± 0.3

ND

ND

ND

16

2.4 ± 0.4

175.9 ± 9.0

44.5 ± 2.4

ND

7.0 ± 0.2

303.5 ± 5.8

ND

151.1 ± 5.5

298.6 ± 15.9

ND

ND

46.2 ± 1.7

65.7 ± 3.3

191.5 ± 13.5

ND

42.2 ± 0.2

57.4 ± 1.9

ND

52.0 ± 4.9

4.8 ± 0.2

ND

17a

ND

ND

ND

1.2 ± 0.2

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

21

1.2 ± 0.2

116.7 ± 7.7

28.8 ± 0.9

ND

3.5 ± 0.3

198.8 ± 9.3

ND

104.0 ± 4.8

226.3 ± 12.3

ND

ND

38.4 ± 0.8

32.6 ± 0.7

141.5 ± 6.3

ND

1.6 ± 0.1

44.0 ± 0.5

ND

40.6 ± 2.9

3.6 ± 0.3

ND

27

39.7 ± 2.2

49.3 ± 2.2

10.3 ± 0.2

12.9 ± 0.6

307.2 ± 24.6

99.6 ± 1.3

ND

60.9 ± 2.3

146.6 ± 4.6

ND

ND

18.7 ± 1.5

39.9 ± 0.9

64.7 ± 10.0

ND

57.3 ± 4.6

49.4 ± 2.6

ND

25.6 ± 2.7

51.3 ± 2.0

ND

29

4.0 ± 0.2

3.0 ± 0.2

0.8 ± 0.2

1.3 ± 0.1

28.2 ± 1.1

5.9 ± 0.1

ND

2.7 ± 0.3

9.0 ± 0.6

ND

ND

1.8 ± 0.5

1.3 ± 0.2

4.4 ± 0.3

ND

4.0 ± 0.1

3.0 ± 0.2

ND

1.4 ± 0.3

5.4 ± 0.1

ND

41a

ND

0.9 ± 0.4

0.3 ± 0.0

ND

ND

1.4 ± 0.6

ND

2.7 ± 0.1

2.6 ± 0.5

ND

ND

ND

ND

2.4 ± 0.1

ND

ND

ND

ND

ND

ND

ND

Subtotal

125.1 ± 3.7

403.5 ± 19.0

128.4 ± 8.3

79.7 ± 0.6

800.7 ± 58.2

763.7 ± 40.0

607.9 ± 14.8

422.4 ± 33.3

853.5 ± 34.7

164.1 ± 4.3

379.5 ± 10.4

194.0 ± 11.2

172.1 ± 4.6

495.0 ± 31.5

135.0 ± 10.3

230.8 ± 11.5

234.1 ± 6.4

205.6 ± 3.7

153.4 ± 12.4

185.6 ± 4.7

499.7 ± 13.9

Isorhamnetin derivatives (17)

Mono

64a

6.4 ± 1.4

ND

0.9 ± 0.2

1.5 ± 0.2

ND

ND

ND

2.0 ± 0.3

ND

3.4 ± 0.1

7.5 ± 0.1

1.7 ± 0.1

2.5 ± 0.8

ND

1.8 ± 0.1

7.0 ± 2.6

2.9 ± 0.4

13.3 ± 1.7

3.0 ± 0.5

5.1 ± 1.1

ND

66a

2.8 ± 0.1

ND

1.2 ± 0.2

1.1 ± 0.0

ND

ND

ND

1.4 ± 0.1

ND

4.4 ± 0.4

8.8 ± 0.6

1.2 ± 0.1

2.0 ± 0.2

ND

2.5 ± 0.0

5.0 ± 0.0

2.2 ± 0.3

15.5 ± 0.7

3.1 ± 0.4

2.8 ± 0.3

ND

Di

31

ND

ND

8.5 ± 0.2

ND

ND

ND

ND

8.6 ± 0.7

ND

45.8 ± 4.1

103.8 ± 4.9

8.0 ± 1.0

6.0 ± 0.2

ND

33.4 ± 1.7

1.6 ± 0.0

7.0 ± 1.0

1.2 ± 0.3

13.2 ± 1.5

ND

ND

32a

ND

ND

5.5 ± 0.2

ND

ND

ND

ND

4.3 ± 0.7

ND

40.5 ± 3.1

65.3 ± 3.3

6.1 ± 0.4

1.9 ± 0.3

ND

33.1 ± 5.0

0.6 ± 0.0

4.4 ± 0.1

ND

5.4 ± 0.4

ND

ND

44a

ND

ND

ND

13.0 ± 0.6

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

47

1.8 ± 0.1

ND

3.3 ± 0.3

ND

ND

ND

ND

2.6 ± 0.3

ND

27.7 ± 1.7

54.6 ± 3.6

12.4 ± 0.6

1.4 ± 0.2

ND

20.9 ± 1.7

3.0 ± 0.6

3.0 ± 0.5

54.9 ± 1.9

5.3 ± 1.3

2.4 ± 0.1

ND

51a

ND

ND

ND

22.4 ± 1.1

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

55a

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.1 ± 0.1

1.6 ± 0.0

ND

ND

ND

ND

ND

ND

1.5 ± 0.0

ND

ND

ND

60

44.3 ± 0.8

ND

3.9 ± 0.1

23.0 ± 0.7

ND

ND

ND

6.7 ± 0.3

ND

ND

ND

6.9 ± 0.0

13.6 ± 0.4

ND

ND

47.8 ± 1.5

15.3 ± 0.1

ND

18.4 ± 1.4

24.7 ± 0.2

ND

62

48.8 ± 0.1

ND

2.6 ± 0.2

29.4 ± 1.8

ND

ND

ND

5.1 ± 0.2

ND

ND

ND

7.0 ± 0.2

8.7 ± 0.1

ND

ND

56.6 ± 1.1

17.2 ± 0.7

ND

16.1 ± 1.0

32.3 ± 0.4

ND

Tri

12a

ND

ND

ND

4.8 ± 0.1

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.1 ± 0.4

ND

ND

ND

15a

ND

ND

ND

17.9 ± 0.5

ND

ND

ND

ND

ND

ND

1.2 ± 0.2

ND

ND

ND

ND

ND

ND

1.1 ± 0.1

ND

ND

ND

22a,b

1.2 ± 0.0

ND

10.2 ± 1.0

ND

ND

ND

ND

25.5 ± 2.6

ND

ND

ND

16.8 ± 0.5

21.6 ± 0.6

ND

ND

0.3 ± 0.1

26.2 ± 0.6

ND

14.7 ± 3.8

1.1 ± 0.1

ND

23a,b

ND

ND

22.2 ± 0.6

ND

ND

ND

ND

29.3 ± 0.8

ND

ND

ND

13.1 ± 1.2

66.3 ± 3.4

ND

ND

1.1 ± 0.3

36.4 ± 1.8

ND

70.5 ± 2.5

2.0 ± 0.3

ND

33a,b

31.8 ± 0.3

ND

3.8 ± 0.2

12.8 ± 0.7

ND

ND

ND

6.4 ± 0.0

ND

ND

ND

6.3 ± 0.4

8.5 ± 0.2

ND

ND

15.5 ± 0.7

16.7 ± 1.5

ND

19.1 ± 2.1

23.9 ± 0.4

ND

34a,b

60.5 ± 2.2

ND

7.4 ± 0.3

23.5 ± 1.3

ND

ND

ND

18.0 ± 0.9

ND

ND

ND

8.6 ± 0.7

28.7 ± 0.5

ND

ND

28.8 ± 1.1

31.3 ± 1.7

ND

45.9 ± 2.5

41.0 ± 1.6

ND

42a,b

3.6 ± 0.6

ND

0.6 ± 0.1

1.2 ± 0.4

ND

ND

ND

1.2 ± 0.1

ND

ND

ND

0.7 ± 0.1

2.5 ± 0.5

ND

ND

3.3 ± 0.8

3.3 ± 0.2

ND

1.5 ± 0.0

4.2 ± 0.5

ND

Subtotal

201.3 ± 5.4

ND

70.0 ± 3.3

150.6 ± 5.2

ND

ND

ND

111.0 ± 5.8

ND

122.8 ± 8.7

242.7 ± 11.1

88.7 ± 2.8

163.6 ± 2.9

ND

91.7 ± 7.3

170.6 ± 6.2

165.9 ± 6.5

88.7 ± 3.2

243.2 ± 8.1

139.5 ± 4.7

ND

Flavonols

412.5 ± 5.9

406.2 ± 18.0

275.1 ± 14.1

359.6 ± 13.7

803.0 ± 58.2

765.6 ± 39.9

609.5 ± 14.5

760.3 ± 53.3

854.0 ± 34.8

572.9 ± 27.8

773.5 ± 29.3

649.9 ± 26.4

484.5 ± 9.6

495.0 ± 31.5

536.1 ± 43.1

463.6 ± 17.3

776.3 ± 22.3

378.8 ± 7.3

611.8 ± 39.4

674.8 ± 24.2

499.7 ± 13.9

Flavones (9)

Luteolin derivatives (4)

 

76

2.0 ± 0.2

0.2 ± 0.0

2.5 ± 0.1

1.1 ± 0.1

ND

ND

ND

2.3 ± 0.2

ND

4.3 ± 0.7

3.8 ± 0.3

2.1 ± 0.1

4.9 ± 0.4

ND

2.8 ± 0.1

2.0 ± 0.2

3.0 ± 0.2

5.3 ± 0.5

2.5 ± 0.1

4.7 ± 0.4

ND

48

0.7 ± 0.0

ND

ND

ND

ND

ND

ND

0.7 ± 0.3

ND

ND

ND

ND

ND

ND

ND

0.4 ± 0.0

0.3 ± 0.1

ND

1.1 ± 0.0

0.6 ± 0.1

ND

61

ND

ND

ND

ND

0.6 ± 0.3

ND

ND

ND

ND

0.5 ± 0.1

ND

ND

ND

ND

0.5 ± 0.1

ND

ND

1.2 ± 0.3

ND

ND

ND

68a

0.9 ± 0.2

ND

0.6 ± 0.1

ND

ND

ND

ND

ND

ND

ND

1.3 ± 0.5

0.7 ± 0.0

ND

ND

1.6 ± 0.2

0.5 ± 0.0

1.0 ± 0.1

1.7 ± 0.3

1.6 ± 0.1

1.3 ± 0.1

ND

Subtotal

3.6 ± 0.2

0.2 ± 0.0

3.1 ± 0.2

1.1 ± 0.1

0.6 ± 0.3

ND

ND

3.0 ± 0.4

ND

4.8 ± 0.8

5.1 ± 0.3

2.8 ± 0.1

4.9 ± 0.4

ND

4.9 ± 0.1

2.9 ± 0.1

4.4 ± 0.3

8.2 ± 0.9

5.3 ± 0.3

6.6 ± 0.5

ND

Apigenin derivatives (3)

 

80

0.7 ± 0.1

2.2 ± 0.1

1.1 ± 0.0

0.7 ± 0.1

7.6 ± 0.7

8.3 ± 0.5

8.1 ± 0.8

0.8 ± 0.0

12.1 ± 1.0

1.1 ± 0.0

1.4 ± 0.1

0.7 ± 0.1

0.8 ± 0.0

4.3 ± 0.2

0.7 ± 0.1

1.6 ± 0.1

1.0 ± 0.1

1.5 ± 0.1

1.0 ± 0.1

1.3 ± 0.1

5.8 ± 0.5

65

ND

0.6 ± 0.0

ND

ND

1.6 ± 0.1

2.7 ± 0.2

3.6 ± 0.1

ND

2.7 ± 0.1

ND

ND

ND

ND

2.6 ± 0.1

ND

ND

ND

ND

ND

ND

1.6 ± 0.0

74a

0.4 ± 0.1

3.0 ± 0.1

ND

ND

3.0 ± 0.3

1.9 ± 0.1

4.3 ± 0.4

ND

2.5 ± 0.1

ND

ND

0.2 ± 0.0

ND

7.2 ± 0.2

ND

0.8 ± 0.1

0.5 ± 0.0

1.2 ± 0.1

0.8 ± 0.2

0.9 ± 0.0

3.4 ± 0.1

Subtotal

1.1 ± 0.2

5.8 ± 0.2

1.1 ± 0.0

0.7 ± 0.1

12.2 ± 1.0

12.9 ± 1.6

16.0 ± 1.2

0.8 ± 0.0

17.3 ± 0.9

1.1 ± 0.0

1.4 ± 0.1

0.9 ± 0.1

0.8 ± 0.0

14.2 ± 0.2

0.7 ± 0.1

2.4 ± 0.3

1.5 ± 0.1

2.6 ± 0.2

1.7 ± 0.2

2.2 ± 0.1

10.7 ± 0.5

Chrysoeriol derivatives (2)

 

67

1.2 ± 0.0

ND

0.5 ± 0.1

1.1 ± 0.1

ND

ND

ND

ND

ND

0.8 ± 0.0

0.6 ± 0.1

ND

0.9 ± 0.1

ND

1.0 ± 0.1

0.9 ± 0.0

0.6 ± 0.1

1.0 ± 0.1

1.2 ± 0.2

0.9 ± 0.1

ND

 

75a

1.9 ± 0.1

ND

1.6 ± 0.1

0.8 ± 0.1

ND

ND

ND

1.1 ± 0.1

ND

1.4 ± 0.1

1.2 ± 0.0

1.1 ± 0.1

1.4 ± 0.1

ND

2.4 ± 0.2

1.4 ± 0.1

1.6 ± 0.0

2.6 ± 0.1

2.0 ± 0.1

1.4 ± 0.0

ND

Subtotal

3.1 ± 0.1

ND

2.1 ± 0.2

1.9 ± 0.2

ND

ND

ND

1.1 ± 0.1

ND

2.2 ± 0.1

1.8 ± 0.1

1.1 ± 0.1

2.3 ± 0.1

ND

3.4 ± 0.3

2.3 ± 0.1

2.2 ± 0.4

3.6 ± 0.1

3.2 ± 0.2

2.3 ± 0.1

ND

Flavones

7.9 ± 0.3

3.6 ± 0.2

6.3 ± 0.1

3.6 ± 0.2

12.9 ± 1.0

12.9 ± 1.6

16.0 ± 1.2

4.9 ± 0.3

17.3 ± 0.9

8.0 ± 0.8

8.3 ± 0.3

4.8 ± 0.2

8.1 ± 0.2

14.2 ± 0.2

9.0 ± 0.5

7.6 ± 0.3

8.1 ± 0.8

14.4 ± 0.7

10.3 ± 0.4

11.0 ± 1.0

10.7 ± 0.5

Isoflavones (19)

Daidzein derivatives (4)

 

73

1.1 ± 0.2

6.9 ± 0.3

0.6 ± 0.3

0.4 ± 0.1

0.5 ± 0.0

0.5 ± 0.1

0.9 ± 0.1

0.6 ± 0.0

1.0 ± 0.1

0.5 ± 0.1

1.0 ± 0.1

2.3 ± 0.2

1.1 ± 0.1

0.6 ± 0.0

ND

1.6 ± 0.2

0.8 ± 0.0

0.7 ± 0.0

2.2 ± 0.7

0.5 ± 0.2

1.1 ± 0.3

9

ND

2.5 ± 0.5

1.0 ± 0.1

0.6 ± 0.3

1.5 ± 0.4

1.1 ± 0.1

1.1 ± 0.1

1.0 ± 0.1

1.9 ± 0.2

5.8 ± 1.6

5.0 ± 0.3

1.2 ± 0.5

1.0 ± 0.3

0.9 ± 0.1

0.6 ± 0.1

1.3 ± 0.1

0.7 ± 0.1

0.4 ± 0.2

1.2 ± 0.2

0.6 ± 0.1

ND

50a

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.3 ± 0.1

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

59

4.6 ± 0.3

11.0 ± 0.3

1.1 ± 0.0

1.2 ± 0.7

9.1 ± 0.6

2.2 ± 0.9

3.7 ± 0.1

2.0 ± 0.1

4.5 ± 1.4

2.6 ± 0.3

9.5 ± 0.6

3.7 ± 0.4

2.5 ± 0.3

2.7 ± 0.1

2.1 ± 0.2

6.6 ± 0.8

3.5 ± 0.1

4.5 ± 0.1

4.0 ± 0.4

2.5 ± 0.5

2.4 ± 0.2

Subtotal

5.7 ± 0.1

20.5 ± 1.0

2.7 ± 0.5

2.1 ± 0.7

11.2 ± 0.4

3.8 ± 0.7

5.8 ± 0.2

3.6 ± 0.0

7.4 ± 1.1

8.9 ± 2.0

15.8 ± 0.8

7.3 ± 0.3

4.6 ± 1.7

4.2 ± 1.2

2.7 ± 0.3

9.5 ± 0.4

4.9 ± 0.4

5.6 ± 0.4

7.4 ± 0.5

3.6 ± 0.8

3.5 ± 0.3

Glycitein derivatives (1)

 

19

1.4 ± 0.3

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

Subtotal

1.4 ± 0.3

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

Genistein derivatives (6)

 

79

4.7 ± 0.3

10.5 ± 0.1

4.7 ± 0.2

3.7 ± 0.2

4.1 ± 0.5

3.7 ± 0.1

4.9 ± 0.7

2.3 ± 0.2

4.2 ± 0.3

2.3 ± 0.4

1.0 ± 0.1

5.9 ± 0.3

8.1 ± 0.7

6.1 ± 0.9

2.6 ± 0.2

5.5 ± 0.2

2.7 ± 0.3

2.2 ± 0.2

5.5 ± 0.6

3.7 ± 0.4

3.8 ± 0.4

49

39.2 ± 1.5

21.3 ± 0.2

8.0 ± 0.7

19.1 ± 5.8

33.5 ± 1.8

39.1 ± 2.0

44.5 ± 1.7

23.2 ± 0.6

54.5 ± 2.4

10.7 ± 4.1

17.2 ± 2.4

13.5 ± 4.8

23.9 ± 2.7

17.9 ± 0.4

7.2 ± 0.5

33.6 ± 2.5

28.4 ± 3.0

12.5 ± 0.6

47.1 ± 7.0

17.3 ± 3.0

16.3 ± 0.7

36a

ND

ND

ND

1.3 ± 0.4

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

45a

1.3 ± 0.4

ND

ND

1.1 ± 0.2

ND

1.0 ± 0.2

ND

ND

8.7 ± 1.2

ND

ND

ND

ND

ND

ND

ND

0.3 ± 0.0

0.4 ± 0.0

1.0 ± 0.2

0.8 ± 0.3

ND

69a

2.5 ± 0.4

3.3 ± 0.0

2.0 ± 0.5

1.1 ± 0.0

4.4 ± 0.5

1.0 ± 0.2

2.6 ± 0.3

2.0 ± 0.5

2.1 ± 0.6

3.0 ± 0.2

2.8 ± 0.1

2.5 ± 0.5

2.5 ± 0.3

3.5 ± 0.4

3.6 ± 0.3

2.1 ± 0.5

2.7 ± 0.5

2.0 ± 0.2

3.3 ± 0.4

2.4 ± 0.7

4.1 ± 0.2

70

44.4 ± 1.2

53.9 ± 0.4

36.4 ± 2.9

23.3 ± 1.7

76.5 ± 5.9

18.5 ± 1.2

56.1 ± 2.4

41.5 ± 2.9

40.1 ± 1.1

57.0 ± 4.3

50.3 ± 1.4

46.6 ± 2.4

41.6 ± 1.0

64.0 ± 1.5

68.0 ± 1.5

42.6 ± 2.6

51.9 ± 2.0

48.4 ± 0.3

66.7 ± 2.7

47.2 ± 2.3

75.2 ± 1.6

Subtotal

92.0 ± 6.2

89.0 ± 0.4

51.1 ± 4.8

49.6 ± 3.5

49.6 ± 3.5

63.2 ± 2.2

108.2 ± 2.9

69.1 ± 4.0

109.6 ± 1.2

72.9 ± 2.6

71.3 ± 4.2

68.5 ± 6.9

76.1 ± 3.3

91.6 ± 2.8

81.3 ± 1.8

83.8 ± 4.3

86.6 ± 6.0

65.5 ± 8.7

123.5 ± 9.3

71.4 ± 2.4

99.3 ± 2.3

Tectorigenin derivatives (3)

 

81a

0.7 ± 0.1

1.4 ± 0.5

0.6 ± 0.1

0.7 ± 0.1

ND

ND

ND

0.4 ± 0.0

ND

ND

ND

0.4 ± 0.0

0.4 ± 0.0

ND

ND

ND

ND

ND

ND

0.9 ± 0.0

ND

56a

ND

ND

ND

2.6 ± 0.1

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.7 ± 0.1

1.0 ± 0.2

ND

ND

2.6 ± 0.1

ND

ND

71a

10.2 ± 0.1

2.2 ± 0.1

5.4 ± 0.6

8.7 ± 0.5

3.4 ± 0.3

0.5 ± 0.1

2.3 ± 0.5

1.8 ± 0.2

ND

6.4 ± 0.6

2.3 ± 0.1

5.4 ± 0.5

2.9 ± 0.3

2.5 ± 0.2

8.2 ± 0.2

4.6 ± 0.6

4.3 ± 0.2

5.6 ± 0.4

11.2 ± 0.5

5.1 ± 0.1

2.4 ± 0.2

Subtotal

10.9 ± 0.1

3.6 ± 0.5

6.0 ± 0.7

12.0 ± 0.6

3.4 ± 0.3

0.5 ± 0.1

2.3 ± 0.5

2.2 ± 0.4

ND

6.4 ± 0.6

2.3 ± 0.1

5.8 ± 0.6

3.3 ± 0.3

2.5 ± 0.2

8.9 ± 0.3

5.6 ± 0.7

4.3 ± 0.2

5.6 ± 0.4

13.9 ± 0.6

6.0 ± 0.1

2.4 ± 0.2

Afromosin derivatives (3)

 

83

ND

8.4 ± 0.1

ND

ND

ND

ND

1.0 ± 0.1

ND

ND

ND

ND

1.8 ± 0.1

ND

0.5 ± 0.1

ND

0.3 ± 0.1

ND

ND

2.4 ± 0.1

ND

ND

72

ND

ND

ND

ND

ND

0.9 ± 0.3

0.2 ± 0.1

ND

1.3 ± 0.2

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

78a

0.7 ± 0.2

1.9 ± 0.2

1.4 ± 0.4

ND

ND

1.1 ± 0.2

2.5 ± 0.2

1.0 ± 0.2

1.6 ± 0.4

0.2 ± 0.1

2.5 ± 0.3

1.7 ± 0.1

1.2 ± 0.3

1.7 ± 0.2

1.5 ± 0.3

0.8 ± 0.2

1.8 ± 0.3

0.5 ± 0.1

4.2 ± 0.3

2.5 ± 0.3

2.2 ± 0.4

Subtotal

0.7 ± 0.2

10.4 ± 0.3

1.4 ± 0.4

ND

ND

2.1 ± 0.3

3.8 ± 0.4

1.0 ± 0.2

2.9 ± 0.5

0.2 ± 0.1

2.5 ± 0.3

3.5 ± 0.1

1.2 ± 0.3

2.2 ± 0.2

1.5 ± 0.3

1.1 ± 0.2

1.8 ± 0.3

0.5 ± 0.1

6.6 ± 0.2

2.5 ± 0.5

2.2 ± 0.4

Formononetin derivatives (2)

 

82

0.4 ± 0.0

1.9 ± 0.2

ND

ND

ND

ND

0.6 ± 0.1

ND

ND

ND

ND

1.2 ± 0.1

ND

1.0 ± 0.1

ND

2.4 ± 0.0

ND

ND

1.1 ± 0.1

ND

ND

77

1.3 ± 0.2

5.3 ± 0.1

ND

ND

2.1 ± 0.5

1.0 ± 0.4

0.9 ± 0.1

1.4 ± 0.2

1.4 ± 0.0

2.4 ± 0.7

0.5 ± 0.1

1.5 ± 0.5

0.4 ± 0.2

3.0 ± 0.4

1.3 ± 0.2

2.7 ± 0.1

1.3 ± 0.3

3.5 ± 0.1

1.6 ± 0.3

0.6 ± 0.2

2.1 ± 0.2

Subtotal

1.6 ± 0.2

7.2 ± 0.2

ND

ND

2.1 ± 0.5

1.0 ± 0.4

1.4 ± 0.1

1.4 ± 0.2

1.4 ± 0.0

2.4 ± 0.7

0.5 ± 0.1

2.7 ± 0.5

0.4 ± 0.2

4.0 ± 0.3

1.3 ± 0.2

5.0 ± 0.2

1.3 ± 0.3

3.5 ± 0.1

2.7 ± 0.2

0.6 ± 0.2

2.1 ± 0.2

Isoflavones

112.4 ± 3.9

130.6 ± 0.8

61.2 ± 8.0

63.7 ± 3.5

135.2 ± 5.1

70.6 ± 1.8

121.4 ± 2.7

77.3 ± 4.2

121.3 ± 1.9

90.7 ± 1.1

92.5 ± 0.5

87.8 ± 5.5

85.6 ± 1.9

104.5 ± 1.9

95.9 ± 1.5

105.1 ± 8.1

98.4 ± 7.9

15.1 ± 0.5

154.0 ± 5.6

84.1 ± 4.1

109.5 ± 1.3

Total

532.8 ± 18.6

542.8 ± 16.3

342.5 ± 17.2

427.0 ± 15.7

951.1 ± 33.4

849.1 ± 43.4

747.0 ± 18.2

842.5 ± 56.1

992.7 ± 35.2

671.7 ± 30.6

874.2 ± 31.0

742.5 ± 9.3

578.2 ± 11.7

613.6 ± 30.0

640.9 ± 42.3

576.3 ± 26.0

882.7 ± 29.4

408.4 ± 1.9

776.1 ± 34.1

769.9 ± 25.3

619.9 ± 12.6

  1. Each value calculated as mean values ± SD (n = 3) using internal standards (6-methoxyluteolin and 6-methoxyflavone for flavonol-flavone and isoflavone, respectively). SL, soybean leaf; ND, not detected.
  2. a, new flavonoid in soybean leaves; b, newly named. Compound names are presented according to peak numbers in Table 1.
  3. Significant values are in [bold].