Extended Data Fig. 1: Scope for the coupling of aryl bromides with polysubstituted ethylenes by means of TFU photoredox catalysis.

Examples of Mizoroki–Heck couplings between aryl bromides and polysubstituted alkenes using TFU technology. Reaction conditions: aryl bromide (10−2 M), polysubstituted alkenes (0.1 M), BOPHY (10−4 M) and DPA (10−3 M), 3 ml of ACN/DMA 5/1 v/v using a blue laser pointer (445 nm ± 10) under nitrogen atmosphere during 5 h. i This reaction was carried out using 2–acetyl–5–chlorothiophene.