Merging the advantages of homogeneous and heterogeneous catalysts is a useful strategy for creating improved catalytic systems. Now, a concept has been developed that uses single Pd atoms — supported within liquid alloy droplets — that emerge from the droplet subsurface and interior to react with molecules approaching from the gas phase.
This is a preview of subscription content, access via your institution
Relevant articles
Open Access articles citing this article.
-
Dry reforming of methane over gallium-based supported catalytically active liquid metal solutions
Communications Chemistry Open Access 18 October 2023
-
Direct C(sp2)–H Borylation of Arenes Using Ir-bpy Porous Organic Polymers
Topics in Catalysis Open Access 17 May 2023
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
27,99 € / 30 days
cancel any time
Subscribe to this journal
Receive 12 print issues and online access
269,00 € per year
only 22,42 € per issue
Buy this article
- Purchase on SpringerLink
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout

References
Peterson, E. J. et al. Nat. Commun. 4885 (2014).
Sterrer, M. et al. Phys. Rev. Lett. 98, 096107 (2007).
Bruix, A. et al. Angew. Chem. Int. Ed. 53, 10525 (2014).
Bliem, R. et al. Angew. Chem. Int. Ed. 54, 13999–14002 (2015).
Soma-Noto, Y. & Sachtler, W. M. H. J. Catal. 32, 315–324 (1974).
Kugler, E. L. & Boudart, M. J. Catal. 59, 201–210 (1979).
Chen, M. S., Kumar, D., Yi, C.W. & Goodman, D. W. Science 310, 291–293 (2005).
Kyriakou, G. et al. Science 335, 1209–1212 (2012).
Taccardi. et al. Nat. Chem. 9, 862–867 (2017).
Armbrüster, M., Schlögl, R. & Grin, Y. Sci. Technol. Adv. Mater. 15, 034803 (2014).
Föttinger, K. & Rupprechter, G. Acc. Chem. Res. 47, 3071–3079 (2014).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rupprechter, G. Popping up to the surface. Nature Chem 9, 833–834 (2017). https://doi.org/10.1038/nchem.2849
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.2849
This article is cited by
-
Dry reforming of methane over gallium-based supported catalytically active liquid metal solutions
Communications Chemistry (2023)
-
Direct C(sp2)–H Borylation of Arenes Using Ir-bpy Porous Organic Polymers
Topics in Catalysis (2023)
-
Free-atom-like d states in single-atom alloy catalysts
Nature Chemistry (2018)