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An antisolvent-seeding approach to produce stable flexible tandem solar cells

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An antisolvent-seeding strategy enhanced self-assembled monolayer formation, enabling the growth of high-quality perovskite top cells on flexible Cu(In,Ga)(S,Se)2 bottom cells. A 1 cm2 flexible tandem solar cell produced using this approach achieved a certified efficiency of 23.8% and is photostable and mechanically durable.

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Fig. 1: Antisolvent-seeding to enhance SAM adsorption for flexible perovskite/CIGS tandems.

References

  1. Al-Ashouri, A. et al. Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells. Energy Environ. Sci. 12, 3356–3369 (2019). This paper introduces the use of SAMs as a contact material in perovskite-based solar cells.

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  2. Nie, H.-Y., Walzak, M. J. & McIntyre, N. S. Delivering octadecylphosphonic acid self-assembled monolayers on a Si wafer and other oxide surfaces. J. Phys. Chem. B 110, 21101–21108 (2006). This paper demonstrated that low-polarity solvents provide a thermodynamically favourable environment for the adsorption of SAMs.

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  3. Zheng, X. et al. Co-deposition of hole-selective contact and absorber for improving the processability of perovskite solar cells. Nat. Energy 8, 462–472 (2023). This paper demonstrates the co-deposition of perovskites and SAMs.

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This is a summary of: Ying, Z. et al. Antisolvent seeding of self assembled monolayers for flexible monolithic perovskite/Cu(In,Ga)Se2 tandem solar cells. Nat. Energy https://doi.org/10.1038/s41560-025-01760-6 (2025).

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An antisolvent-seeding approach to produce stable flexible tandem solar cells. Nat Energy 10, 677–678 (2025). https://doi.org/10.1038/s41560-025-01766-0

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