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Showing 1–5 of 5 results
Advanced filters: Author: Dmitry Khakhulin Clear advanced filters
  • In time-resolved measurements it is crucial to know the time delay between the exciting and probing light pulses. Here the authors demonstrate a self-referencing common-path interferometer method measuring the arrival time between the X-ray free electron laser and the optical pulse to the target and thus their inherent timing jitter.

    • Michael Diez
    • Henning Kirchberg
    • Christian Bressler
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-9
  • The change from low-spin hexacoordinated to high-spin pentacoordinated domed form in heam upon ligand detachment and the reverse process underlie the respiratory function. The authors, using femtosecond time-resolved X-ray emission spectroscopy, capture the transient states connecting the two forms in myoglobin-NO upon NO photoinduced detachment.

    • Dominik Kinschel
    • Camila Bacellar
    • Majed Chergui
    ResearchOpen Access
    Nature Communications
    Volume: 11, P: 1-8
  • Nonadiabatic excited state processes involve mixing of electronic and nuclear wavefunctions, which are difficult to disentangle. Here the authors explore by time-resolved X-ray absorption near edge structure the wavepacket dynamics of a copper(I)-phenanthroline complex, resolving different vibrational modes.

    • Tetsuo Katayama
    • Thomas Northey
    • Thomas J. Penfold
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-8
  • Yaroshevich et al. present a chemical reaction mechanism of a 35-kDa blue light-triggered photoreceptor, the Orange Carotenoid Protein (OCP). They find that photoactivation critically involves the transient formation of a protonated ketocarotenoid (oxocarbenium cation) state. This study suggests the role of charge-transfer states during OCP photoconversion.

    • Igor A. Yaroshevich
    • Eugene G. Maksimov
    • Mikhail P. Kirpichnikov
    ResearchOpen Access
    Communications Biology
    Volume: 4, P: 1-13