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Advanced filters: Author: Merle Arrowsmith Clear advanced filters

  • Two neutral compounds containing a zero-valent s-block metal, beryllium, have now been isolated and fully characterized. Structural characterization, supported by calculations, show that these brightly coloured complexes adopt a closed-shell singlet configuration with a Be(0) metal centre and an unusually strong three-centre two-electron Ï€-bond across the C–Be–C unit.

    • Merle Arrowsmith
    • Holger Braunschweig
    • Julia K. Schuster
    Research
    Nature Chemistry
    Volume: 8, P: 890-894