Amide group-containing polymer functionalized on carbon surfaces selectively interacts with the Co precursor, resulting in Co–N bond formation on PtCo nanoparticle surfaces. The electron transfer from Co to Pt is enhanced due to increased electronegativity difference between Pt and Co. In addition, the dissolution of Co and Pt during the oxygen reduction reaction (ORR) is retarded by the selective passivation of surface Co atoms and the decrease in the O-binding energy of surface Pt atoms. As a result, the catalytic activity and durability of the hybrid PtCo nanoparticles for the ORR are significantly improved by the electronic ensemble effects.
- Namgee Jung
- Satadeep Bhattacharjee
- Sung Jong Yoo