Fig. 3: Substrate scope and functional group compatibility of the SS-thiosulfonates. | Nature Communications

Fig. 3: Substrate scope and functional group compatibility of the SS-thiosulfonates.

From: Photo-induced decarboxylative C-S bond formation to access sterically hindered unsymmetric S-alkyl thiosulfonates and SS-alkyl thiosulfonates

Fig. 3

Reaction conditions: 1 (0.2 mmol), 2 (2 equiv, 0.4 mmol), 4CzIPN (2 mol%, 0.004 mmol), Cu(OTf)2 (20 mol%, 0.04 mmol), (BuO)2P(O)OH (2 equiv, 0.4 mmol), EA (2 mL) at room temperature (rt), 5 W blue LEDs, 12 h in N2. EA ethyl acetate.

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