A freestanding three-dimensional graphdiyne-hollowed FeCoNi Prussian blue analog electrode (h-FeCoNi PBA@GDY) with highly selective and active interfaces was synthesized by in situ growth of GDY layer on the surface of h-FeCoNi PBA for electrocatalytic nitrate reduction reaction (ECNtRR) at ambient temperatures and pressures. Experimental results demonstrate the presence of the unique incomplete charge transfer between metal atoms and GDY can effectively enhance the intrinsic activity and the ability to increase the active sites of the electrocatalyst, promote fast redox switching, and high-density charge transport at the interface resulting in high reaction selectivity, activity and stability for ammonia production.
- Yaqi Gao
- Huimin Liu
- Yuliang Li